Closing the Recycling Loop of PEM Electrolyzer: Synthesis of Ir Precursor from Spent Electrocatalyst

Green Chemistry
pp.
360-363
Abstract

This study investigates hydrometallurgical recycling of iridium (Ir) from proton exchange membrane (PEM) electrocatalyst - critical for Europe's decarbonization goals. Results demonstrate the efficient synthesis of ammonium hexachloroiridate ((NH4)2IrCl6) via precipitation, which serves as a precursor for new electrocatalysts, supporting circular economy strategies in PEM electrode production.

Author (co-authors)
First name Last name Institutional affiliation E-mail Phone number ORCID ID Academic status, position Institution address Author contribution(s) Institutional affiliation
Lesia
Sandig-Predzymirska
lesia.sandig-predzymirska@inemet.tu-freiberg.de
0000-0003-1155-6250
Dr. rer. nat., Group leader
Institute for Nonferrous Metallurgy and Purest Materials (INEMET), TU Bergakademie Freiberg, GERMANY, 09599 Freiberg, Leipziger Str. 34
Conceptualization
Data Curation
Formal Analysis
Investigation
Methodology
Writing – Original Draft Preparation
TU Bergakademie Freiberg
Alexandros
Charitos
alexandros.charitos@inemet.tu-freiberg.de
Prof., Institute director
Institute for Nonferrous Metallurgy and Purest Materials (INEMET), TU Bergakademie Freiberg, GERMANY, 09599 Freiberg, Leipziger Str. 34
Conceptualization
Funding Acquisition
Supervision
Writing – Review & Editing
TU Bergakademie Freiberg
References

[1] European Commission. (2020). A hydrogen strategy for a climate-neutral Europe (COM 2020, 301 final).

[2] Kumar, S. S., & Lim, H. (2023). Recent advances in hydrogen production through proton exchange membrane water electrolysis – a review. Sustainable Energy & Fuels, 7, 3560–3583. DOI: 10.1039/D3SE00336A

[3] Melke, J., Maletzko, A., Gomez Villa, E. D., Bornet, A., Wiberg, G. K. H., Arenz, M., Sandig-Predzymirska, L., Thiere, A., Charitos, A., Stelter, M., Wang, Z., Pitscheider, S., Bertheussen, E., Pedersen, C. M., Finsdóttir, S., Kokborg, M. S., Berman, D. G., Dalvang, S., Müller, S. S., Seidel, F., Seselj, N., Höglinger, M., Kartusch, S., Eder, J., Macherhammer, M., Trattner, A., & Kallesøe, C. (2024). Recycalyse – New Sustainable and Recyclable Catalytic Materials for Proton Exchange Membrane Electrolysers. Chem. Ing. Tech., 96(1–2), 1–18. DOI: 10.1002/cite.202300143

[4] Clayton, J. A., & Walton, R. I. (2022). Development of New Mixed-Metal Ruthenium and Iridium Oxides as Electrocatalysts for Oxygen Evolution: Part II. Johnson Matthey Technol. Rev., 66(4), 406–417. DOI: 10.1595/205651322X16605694237357

[5] Burlakovs, J., Vincevica-Gaile, Z., Krievans, M., Jani, Y., Horttanainen, M., Pehme, K.-M., Dace, E., Setyobudi, R. H., Pilecka, J., Denafas, G., Grinfelde, I., Bhatnagar, A., Rud, V., Rudovica, V., Mersky, R. L., Anne, O., Kriipsalu, M., Ozola-Davidane, R., Tamm, T., & Klavins, M. (2020). Platinum Group Elements in Geosphere and Anthroposphere: Interplay among the Global Reserves, Urban Ores, Markets and Circular Economy. Minerals, 10, 558. DOI: 10.3390/min10060558

[6] Sandig-Predzymirska, L., Barreiros, T. V., Weigelt, A., Pitscheider, S., Pedersen, C. M., Kallesøe, C., Thiere, A., Stelter, M., & Charitos, A. (2025). Recovery of Platinum and Ruthenium from PEM Electrodes via Hydrometallurgical Approach. J. Sustain. Metall., 11, 145–159. DOI: 10.1007/s40831-025-01011-8

[7] Otgonbayar, U., Sandig-Predzymirska, L., Thiere, A., & Charitos, A. (2024). Solvent extraction of Pt, Ru, and Ir using Cyanex 923 in chloride media to develop a recycling route for spent polymer electrolyte membrane (PEM) electrolyzers. Hydrometallurgy, 226, 106303. DOI: 10.1016/j.hydromet.2024.106303

[8] Fine, D. A. (1970). Studies of the iridium(III) and (IV) - chloride system in acid solution. J. Inorg. Nucl. Chem., 32(8), 2731–2742. DOI: 10.1016/0022-1902(70)80323-2